75.​ Kulathungage, L. W.; Kurup, S. S.; Browne, E. A.; Spalink, G. H.; Ward, C. L.; Lord, R. L.; Groysman, S. Efficient carbene transfer reactivity mediated by Fe(II) complexes supported by bulky alkoxides. Chem. Commun. 2024, 60, 7033-7036. (Invited contribution to the Themed Collection: Small Molecule Transformations of Energy Relevance)
74. Blasczak, V.; Murphy, A.; Suntrup, L.; Ngo, K. T.; Reed, B.; Groysman, S.; Grills, D. C.; Rochford, J. Structure activity relationships for second-coordination sphere functional group dependent CO2 reduction by manganese bipyridyl electrocatalysts. ChemCatChem 2024, 16, e202301388.
73. Kaluarachchige Don, U. I.; Buddhika Chandima, A. M.; Gelman, D.; Lord, R. L.; Groysman, S. Design and reactivity of early-late bimetallics as structural and functional models of Mo Cu CODH. Comments Inorg. Chem. 2024, 44, 349-384.
72. Kaluarachchige Don, U. I.; Palmer, Z.; Ward, C. L.; Lord, R. L.; Groysman, S. Combining [MoVIO3] and [M0(CO)3] M=(Mo,Cr) fragments within the same complex: synthesis and reactivity of the single oxo- bridged heterobimetallics supported by xanthene-based heterodinucleating ligands. Inorg. Chem. 2023, 62, 15063-15075.
71. Wannipurage, D.; D'Anjello, S.; Pappalardo, D.; Kulathungage, L. W.; Ward, C. L.; Anderson, D. P.; Groysman, S.; Mazzeo, M. Simple magnesium alkoxides: synthesis, molecular structure, and catalytic behaviour in the ring-opening polymerization of lactide and macrolactones and in the copolymerization of maleic anhydride and propylene oxide. Dalton Trans. 2023, 52, 8077-8091.
70. Dissanayake, A. I.; Hollingsworth, T. S.; Madarang, E.; Hamilton, P. N.; Ward, C. L.; Groysman, S. "Catch-store-release" strategy for the stabilization of 4,4'-Methylene Diphenyl Diisocyanate (4,4'-MDI). Chem. Eur. J. 2023, 29, e202300924. (See here our Cover Feature)
69. Kaluarachchige Don, U. I.; Almaat, A. S.; Ward, C. L.; Groysman, S. Studies relevant to the functional model of Mo-Cu CODH: in situ reactions of Cu(I)-L complexes with Mo(VI) and synthesis of stable structurally characterized heterotetranuclear MoVI2CuI2 Complex. Molecules 2023, 28, 3644. (Invited contribution to the Special Issue: Molybdenum and Tungsten Enzymes—State of the Art in Research)
68. Blasczak, V.; Mckinnon, M.; Suntrup, L.; Aminudin, N. A.; Reed, B.; Groysman, S.; Ertem, M. Z.; Grills, D. C.; Rochford, J. Steric and lewis basicity influence of the second coordination sphere on electrocatalytic CO2 reduction by manganese bipyridyl complexes. Inorg. Chem. 2022, 61, 15784-15800.
​67. Kurup, S. S.; Woodland, N. M.; Lord, R. L.; Groysman, S. Aziridination reactivity of a manganese(II) complex with a bulky chelating bis(alkoxide) ligand. Molecules 2022, 27, 5751.
66. Kurup, S. S.; Groysman, S. Catalytic synthesis of azoarenes via metal-mediated nitrene coupling. Dalton Trans. 2022, 51, 4577-4589.
65. Dissanayake, A. I.; Hollingsworth, T. S.; Kurup, S. S.; Wannipurage, D.; Hamilton, P. N.; Lord, R. L.; Groysman, S. Synthesis, electronic structures, and reactivity of mononuclear and dinuclear low-valent molybdenum complexes in iminopyridine and bis(imino)pyridine ligand environments. J. Inorg. Biochem. 2022, 230, 111744. (Invited contribution to the Special Issue in memory of Richard H. Holm)
64. Kurup, S. S.; Nasser, S.; Ward, C. L.; Groysman, S. Synthesis and structure of a new bulky bis(alkoxide) ligand on a terphenyl platform. Acta Crystallogr. E: Crystallogr. Commun. 2022, 78, 92-96.
63. Balch, A.; Everett, G.; Power, P. P.; Armstrong, W. H.; Kovacs, J.; Stack, T. D. P.; Donahue, J. P.; Gray, T. G.; Groysman, S.; Deng, L. Richard Hadley Holm: A remembrance and a tribute. Comments Inorg. Chem. 2021, 1-48.
62. Wannipurage, D.; Kurup, S. S.; Groysman, S. Heterocoupling of different aryl nitrenes to produce asymmetric azoarenes using iorn-alkoxide catalysis and investigation of the cis-trans isomerism of selected bulky asymmetric azoarenes. Organometallics 2021, 40, 3637-3644.
​​61. Kaluarachchige Don, U. I.; Kurup, S. S.; Hollingsworth, T. S.; Ward, C. L.; Lord, R. L.; Groysman, S. Synthesis and Cu(I)/Mo(VI) reactivity of a bifunctional heterodinucleating ligand on a xanthene platform. Inorg. Chem. 2021, 60, 14655-14666.
60. Groysman, S.; Grass, A. Alkoxide ligands, In Comprehensive Coordination Chemistry III, Constable, E. C.; Parkin, G.; Que, L., Jr, Eds, Elsevier 2021, 158-177.
59. Grass, A.; Kulathungage, L. W.; Wannipurage, D.; Yousif, M.; Ward, C. L.; Groysman, S. Synthesis, characterization, and alkoxide transfer reactivity of dimeric Tl2(OR)2 complexes. Dalton Trans. 2021, 50, 2501-2509.
58. Grass, A.; Bellow, J. A.; Morrison, G.; zur Loye, H.-C.; Lord, R. L.; Groysman, S. One electron reduction transforms high-valent low-spin cobalt alkylidene into high-spin cobalt(II) carbene radical. Chem. Commun. 2020, 56, 8416-8419.
57. Wannipurage, D.; Hollingsworth, T. S.; Santulli, F.; Cozzolino, M.; Lamberti, M.; Groysman, S.; Mazzeo, M. Synthesis of a mononuclear magnesium bis(alkoxide) complex and its reactivity in the ring-opening copolymerization of cyclic anhydrides with epoxides. Dalton Trans. 2020, 49, 2715-2723.
56. Kurup, S. S.; Staples, R. J.; Lord, R. L.; Groysman, S. Synthesis of chromium(II) complexes with chelating bis(alkoxide) ligand and their reactions with organoazides and diazoalkanes. Molecules 2020, 25, 373. (Invited contribution to the Special Issue Organic Azides 2019)
55. Grass, A.; Wannipurage, D.; Lord, R. L.; Groysman, S. Group-transfer chemistry at transition metal centers in bulky alkoxide ligand environments. Coord. Chem. Rev. 2019, 400, 1-16.
54. Kurup, S. S.; Wannipurage, D.; Lord, R. L.; Groysman, S. Tying the alkoxides together: an iron complex of a new chelating bulky bis(alkoxide) demonstrates selectivity for coupling of non-bulky aryl nitrenes. Chem. Commun. 2019, 55, 10780-10783.
53. Grass, A.; Stoian S. A.; Lord, R. L.; Groysman, S. Transition metal-mediated reductive coupling of diazoesters. Chem. Commun. 2019, 55, 8458-8461.
52. Grass, A.; Dewey. N. S.; Lord, R. L.; Groysman, S. Ketenimine Formation Catalyzed by a High Valent Cobalt Carbene in Bulky Alkoxide Ligand Environment. Organometallics 2019, 38, 962-972.
51. Hollingsworth, R. L.; Hollingsworth, T. S.; Groysman, S. Synthesis and Reactivity of Bimetallic Systems Tethered with a 4,5-Diaminoxanthene Linker. In Catalysis by Metal Complexes and Nanomaterials: Fundamentals and Applications; ACS Symposium Series 1317; American Chemical Society: Washington, DC, 2019; pp 1-18.
50. Hollingsworth, R. L.; Beattie, J. W.; Grass, A.; Martin, P. D.; Groysman, S.; Lord, R. L. Reactions of Dicobalt Octacarbonyl with Dinucleating and Mononucleating Bis(imino)pyridine Ligands. Dalton Trans. 2018, 47, 15353-15363.
49. Yousif, M.; Wannipurage, D.; Huizenga, C. D.; Washnock-Schmid, E.; Peraino, N. J.; Ozarowski, A.; Stoian, S. A.; Lord, R. L.; Groysman, S. Catalytic Nitrene Homocoupling by an Iron(II) Bis(alkoxide) Complex: Bulking Up the Alkoxide Enables a Wider Range of Substrates and Provides Insight into the Reaction Mechanism. Inorg. Chem. 2018, 57, 9425-9438.
48. Hollingsworth, T. S.; Hollingsworth, R. L.; Lord, R. L.; Groysman, S. Cooperative Bimetallic Reactivity of a Heterodinuclear Molybdenum-Copper model of Mo-Cu CoDH. Dalton Trans. 2018, 47, 10017-10024. ​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​
47. Hollingsworth, T. S.; Hollingsworth, R. L.; Rosen, T.; Groysman, S. Zinc Bimetallics Suppored by a Xanthene-Bridged Dinucleaing Ligand: Synthesis, Characterization, and Lactide Polymerization Studies. RSC Adv. 2017, 7, 41819-41829.
46. Reed, B. R.; Yousif, M.; Lord, R. L.; McKinnon, M.; Rochford, J.; Groysman, S. Coordination Chemistry and Reactivity of Bis(aldimino)pyridine Nickel Complexes in Four Different Oxidation States. Organometallics 2017, 36, 582-593.
45. Hollingsworth, R. L.; Bheemaraju, A.; Lenca, N.; Lord, R. L.; Groysman, S. Divergent Reactivity of a New Dinuclear Xanthene-Bridged Bis(iminopyridine) di-Nickel Complex with Alkynes. Dalton Trans. 2017, 46, 5605-5616.​
44. Narayanan, R.; McKinnon, M.; Reed, B. R.; Ngo, K. T.; Groysman, S.; Rochford, J. Ambiguous Electrocatalytic CO2 Reduction Behaviour of a Nickel Bis(aldimino)pyridine Pincer Complex. Dalton Trans. 2016, 45, 15285-15289.
43. Bellow, J. A.; Stoian, S. A.; Van Tol, J.; Ozarowski, A.; Lord, R. L.; Groysman, S. Synthesis and Characterization of a Stable High-Valent Cobalt Carbene Complex. J. Am. Chem. Soc. 2016, 138, 5531-5534
42. Yousif, M.; Cabelof, A. C.; Martin, P. D.; Lord, R. L.; Groysman S. Synthesis of a Mononuclear, Non-Square-Planar Chromium(II) Bis(alkoxide) Complex and its Reactivity Toward Organic Carbonyls and CO2. Dalton Trans. 2016, 45, 9794-9804. (Invited Contribution to Special Issue: New Talent: Americas. See Maryam's interview decribing this work here. See our back cover for this issue here.)
41. Beattie, J. W.; SantaLucia, D. J.; White, D. W.; Groysman. S. Oxalate- Templated Synthesis of Di-Zinc Macrocycles. Inorg. Chim. Acta. 2017, 460, 8-16. (Special Issue: New Generation)
40. Bellow, J. A.; Yousif, M.; Groysman, S. Discrete Complexes of 3d Metals with Monodentate Bulky Alkoxide Ligands and Their Reactivity in Bond Activation and Bond Formation Reactions. Comments Inorg. Chem. 2015, 36, 92-122.
39. Yousif, M.; Tjapkes, D.J.; Lord, R.L.; Groysman, S. Catalytic Formation of Asymmetric Carbodiimides at Mononuclear Chromium (II/IV) Bis(alkoxide) Complexes. Organometallics 2015, 34, 5119 - 5128.
38. Bellow, J. A.; Yousif, M.; Fang, D.; Kratz, E. G.; Cisneros, G. A.; Groysman, S. Synthesis and Reactivity of 3d Metal Complexes with the Bulky Alkoxide Ligand [OCtBu2Ph]. Inorg. Chem. 2015, 54, 5624- 5633.
37. Bellow, J. A.; Yousif, M.; Cabelof, A. C.; Lord, R.L.; Groysman, S. Reactivity Modes of an Iron Bis(alkoxide) Complex with Aryl Azides: Catalytic Nitrene Coupling vs Formation of Iron(III) Imido Dimers. Organometallics 2015, 34, 2917-2923.
36. Reed, B.R.; Stoian, S.A.; Lord, R.L.; Groysman S. The Aldimine Effect in Bis(imino)Pyridine Complexes: Non-Planar Nickel(I) Complexes of a Bis(aldimino)pyridine Ligand. Chem. Commun. 2015, 51, 6496-6499. (See our inside back cover here.)
35. Bheemaraju, A.; Beattie, J.W.; Danylyuk, Y.; Rochford, J.; Groysman S. Synthesis, Structures, and Reactivity of Copper(I) Complexes Supported by a Rigid Dinucleating Ligand. Eur. J. Inorg. Chem. 2014, 34, 5865-5873.
34. Beattie, J. W.; White, D.S.; Bheemaraju, A.; Martin, P. D.; Groysman, S. Recyclable Chemosensor for Oxalate Based on Bimetallic Complexes of a Dinucleating Bis(iminopyridine) Ligand. Dalton Trans. 2014, 49, 7979-7986.
33. Bellow, J. A.; Martin, P. D.; Lord, R. L.; Groysman, S. Reductive Coupling of Azides Mediated by an Iron(II) Bis(alkoxide) Complex. Inorg. Chem. 2013, 52, 12335 -12337.
32. Bellow, J. A.; Fang, D.; Kovacevic, N.; Martin, P. D.; Shearer, J.; Cisneros, G. A.; Groysman, S. Novel Alkoxide Cluster Topologies Featuring Rare Seesaw Geometry at Transition Metal Centers. Chem. Eur. J. 2013, 19, 12225-12228.
31. Bheemaraju A.; Beattie, J. W.; Tabasan, E. G.; Martin, P. D.; Lord, R. L.; Groysman, S. Steric and Electronic Effects in the Formation of Carbon Disulfide Reactivity of Dinuclear Nickel Complexes Supported by Bis(iminopyridine) Ligands. Organometallics 2013, 32, 2952-2962.
30.Chambers, M. B.; Groysman, S.; Villigrán, D.; Nocera, D. G.; Iron in a Tris(alkoxide) Ligand Enviroment. Inorg. Chem. 2013, 52, 3159-3169.
29. Bheemaraju A.; Beattie, J. W.; Lord, R. L.; Martin, P. D.; Groysman, S. Carbon Disulfide Binding at Dinuclear and Mononuclear Nickel Complexes Ligated by a Redox-Active Ligand: Iminopyridine Serving as an Accumulator of Redox Equivalents for the Activation of Heteroallenes. Chem. Commun. 2012, 48, 9595-9597.
28. Bheemaraju A.; Lord, R. L.; Müller, P.; Groysman, S. Difference in the Reactivities of H- and Me-Substituted Dinucleating Bis(iminopyridine) Ligands with Nickel(0). Organometallics 2012, 31, 2120-2123.
27. Groysman, S.; Villagrán, D.; Freedman, D. E.; Nocera, D. G. Dinitrogen Binding at Vanadium in the Tris(alkoxide) Ligand Environment. Chem. Commun. 2011, 47, 10242-10244.
​26. Groysman, S.; Villagrán, D.; Nocera, D. G. Pseudo-tetrahedral d0, d1, and d2 Metal-Oxo Cores Within a Tris(alkoxide) Platform. Inorg. Chem. 2010, 49, 10759-10761.​
25. Groysman, S.; Majumdar, A.; Zheng, S.-L.; Holm, R. H. Reactions of Monodithiolene Tungsten(VI) Sulfido Complexes with Copper(I) in Relation to the Structure of the Active Site of Carbon Monoxide Dehydrogenase. Inorg. Chem. 2010, 49, 1082-1089.​
24. Groysman, S.; Holm, R. H. Biomimetic Chemistry of Iron, Nickel, Molybdenum, and Tungsten In Sulfur-Rich Protein Sites. Biochemistry 2009, 48, 2310-2320.
23. Groysman, S., Holm, R. H. A Series of Mononuclear Quasi-Two-Coordinate Copper(I) Complexes Employing a Sterically Demanding Thiolate Ligand. Inorg. Chem. 2009, 48, 621-627.
22. Groysman, S., Wang, J. - J., Tagore, R., Lee, S. C., Holm, R. H. A Biomimetic Approach to Oxidized Sites in the Xanthine Oxidoreductase Family: Synthesis and Stereochemistry of Tungsten(VI) Analogue Complexes. J. Am. Chem. Soc. 2008, 130, 12794-12807.
21. Wang, J. - J.; Groysman, S.; Lee, S. C.; Holm, R. H. Synthesis of Structural Analogues of the Oxidized Sites in the Xanthine Oxidoreductase Enzyme Family. J. Am. Chem. Soc. 2007, 129, 7512-7513.
​20. Groysman, S.; Holm, R. H. Synthesis and Structures of Bis(dithiolene) Tungsten (IV,VI) Thiolate and Selenolate Complexes: Approaches to the Active Sites of Molybdenum and Tungsten Formate Dehydrogenases. Inorg. Chem. 2007, 46, 4090-4102.​
19. Groysman, S.; Sergeeva, E.; Goldberg, I.; Kol, M. Zinc Complexes of the Amine Mono(phenolate) [NOO2] Ligands: Controlling Coordination Modes by Bulk of Phenolate Substituents. Eur. J. Inorg. Chem. 2006, 14, 2739-2745.
​18. Kol, M., Segal, S., Groysman, S. 2008. Stereocontrol in the Polymerization of C4+ α-olefin Monomers. In Stereoselective Polymerization with Single-Site Catalysts L. S. Baugh, J. A. M. Canich Boca Raton, FL.​
17. Gendler, S.; Groysman, S.; Goldschmidt, Z.; Shuster, M.; Kol, M.. Polymerization of 4-methylpentene and Vinylcyclohexane by the Amine Bis(phenolate) Group IV catalysts. J. Polym. Sci., Part A: Polym. Chem. 2006, 44, 1136-1146.
​16. Groysman, S.; Sergeeva, E.; Goldberg, I.; Kol, M. Group IV Complexes of a Tetradentate Amine Mono(phenolate) Ligand: a Second Sidearm Donor Stabilizes Cationic Species. Inorg. Chem. 2005, 44, 8188-8190.​
15. Yeori, A.; Groysman, S.; Goldberg, I.; Kol, M. Diastereoisomerically-Selective Enantiomerically-Pure Titanium Complexes of Chiral Salan Ligands. Inorg. Chem. 2005, 44, 4466-4467.​
14. Groysman, S.; Goldberg, I.; Kol, M.; Goldschmidt, Z. Vanadium(III) and Vanadium(V) Amine Tris(phenolate) Complexes. Inorg. Chem. 2005, 44, 5073-5080.​
13. Groysman, S.; Sergeeva, E.; Goldberg, I.; Kol. M. Salophan complexes with Group IV Metals. Eur. J. Inorg. Chem. 2005, 12, 2480-2485.​
12. Groysman, S.; Goldberg, I., Kol, M., Genizi, E., Goldshmidt, Z. Exploring Routes to Tantalum (V) Alkyl and Alkylidene Complexes Supported by the Amine Tris(Phenolate) ligands. Adv. Syn. Cat. 2005, 347, 409-415.
11. Groysman, S.; Tshuva, E.; Goldberg, I.; Kol, M.; Goldschmidt, Z.; Shuster, M. Diverse Structure-Activity Trends in the Amine Bis(phenolate) Titanium Polymerization Catalysts. Organometallics 2004, 23, 5291-5299.​
10. Groysman, S.; Segal, S.; Goldberg, I.; Kol, M.; Goldschmidt, Z. Ta(V) Complexes of a Bulky Amine Tris(phenolate) Ligand: Steric Inhibition vs. Chelate Effect. Inorg. Chem. Commun. 2004, 7, 938-941.
​9. Groysman, S.; Goldberg, I.; Kol, M.; Genizi, E.; Goldschmidt, Z. Tribenzyl Ta(V) Complexes of Amine Bis(phenolate) Ligands: Investigation of α-Abstraction vs. Ligand Backbone β-Abstraction Paths. Organometallics 2004, 23, 1880-1890.​
8. Yeori, A.; Gendler, S.; Groysman, S.; Goldberg, I.; Kol. M. Salalen: a Hybrid Salan/Salen Tetradentate [ONNO]-Type Ligand and Its Coordination Behavior with Group IV Metals. Inorg. Chem. Commun. 2004, 7, 280-282.​
7. Groysman, S.; Goldberg, I.; Kol, M.; Goldschmidt Z. Pentabenzyltantalum: Straightforward Synthesis, X-ray Structure and Application in the Synthesis of [O2N]TaBn3-Type and [O3N]TaBn2-Type complexes. Organometallics 2003, 22, 3793-3795.​
6. Groysman, S.; Goldberg, I.; Kol, M.; Genizi, E.; Goldschmidt, Z. From THF to Furan: Activity Tuning and Mechanistic Insight via Sidearm Donor Replacement in Group IV Amine Bis(phenolate) Polymerization Catalysts. Organometallics 2003, 22, 3013-3015.
​5. Groysman, S.; Tshuva, E. Y.; Reshef, D.; Gendler, S.; Goldberg, I.; Kol, M.; Goldschmidt, Z.; Shuster, M.; Lidor, G. High-Molecular Weight Atactic Polypropylene prepared by Zirconium Complexes of an Amine Bis(phenolate) Ligand. Isr. J. Chem. 2003, 42, 373-381.
4. Groysman, S.; Goldberg, I.; Kol, M.; Genizi, E.; Goldschmidt, Z. Group IV complexes of an Amine Bis(phenolate) Ligand Featuring a THF Sidearm Donor: From Highly Active to Living Polymerization Catalysts of 1-Hexene. Inorg. Chim. Acta 2003, 345, 137-144. (Protagonists in Chemistry: R. R. Schrock Issue)​
3. Bergman, S.; Reshef, D.; Groysman, S.; Goldberg, I.; Kol, M., Dibenzoeilatin: A Novel Ligand Exhibiting Remarkable Complementary π-π Stacking Interactions. Chem. Commun. 2002, 2374-2375.​
2. Groysman, S.; Segal, S.; Shamis, M.; Goldberg, I.; Kol, M.; Goldschmidt, Z.; Hayut-Salant, E. Tantalum(V) Complexes of an Amine Triphenolate Ligand: a Dramatic Difference in Reactivity Between Two Labile Positions. J. Chem. Soc., Dalton Trans. 2002, 3425-3426.
​​​1. Tshuva, E. Y.; Groysman, S.; Goldberg, I.; Kol, M.; Goldschmidt, Z. [ONXO]-Type Amine Bis(phenolate) Zirconium and Hafnium Complexes as Extremely Active 1-hexene Polymerization Catalysts. Organometallics 2002, 21, 662-670.