75.​ Kulathungage, L. W.; Kurup, S. S.; Browne, E. A.; Spalink, G. H.; Ward, C. L.; Lord, R. L.; Groysman, S. Efficient carbene transfer reactivity mediated by Fe(II) complexes supported by bulky alkoxides. Chem. Commun. 2024, doi:10.1039/D4CC02108H​​​​​​​​​​​​​​
74. Blasczak, V.; Murphy, A.; Suntrup, L.; Ngo, K. T.; Reed, B.; Groysman, S.; Grills, D. C.; Rochford, J. Structure activity relationships for second-coordination sphere functional group dependent CO2 reduction by manganese bipyridyl electrocatalysts. ChemCatChem 2024, 16, e202301388.
73. Kaluarachchige Don, U. I.; Buddhika Chandima, A. M.; Gelman, D.; Lord, R. L.; Groysman, S. Design and reactivity of early-late bimetallics as structural and functional models of Mo Cu CODH. Comments Inorg. Chem. 2024, doi:10.1080/02603594.2023.2298366
72. Kaluarachchige Don, U. I.; Palmer, Z.; Ward, C. L.; Lord, R. L.; Groysman, S. Combining [MoVIO3] and [M0(CO)3] M=(Mo,Cr) fragments within the same complex: synthesis and reactivity of the single oxo- bridged heterobimetallics supported by xanthene-based heterodinucleating ligands. Inorg. Chem. 2023, 62, 15063-15075.
71. Wannipurage, D.; D'Anjello, S.; Pappalardo, D.; Kulathungage, L. W.; Ward, C. L.; Anderson, D. P.; Groysman, S.; Mazzeo, M. Simple magnesium alkoxides: synthesis, molecular structure, and catalytic behaviour in the ring-opening polymerization of lactide and macrolactones and in the copolymerization of maleic anhydride and propylene oxide. Dalton Trans. 2023, 52, 8077-8091.
70. Dissanayake, A. I.; Hollingsworth, T. S.; Madarang, E.; Hamilton, P. N.; Ward, C. L.; Groysman, S. "Catch-store-release" strategy for the stabilization of 4,4'-Methylene Diphenyl Diisocyanate (4,4'-MDI). Chem. Eur. J. 2023, 29, e202300924.
69. Kaluarachchige Don, U. I.; Almaat, A. S.; Ward, C. L.; Groysman, S. Studies relevant to the functional model of Mo-Cu CODH: in situ reactions of Cu(I)-L complexes with Mo(VI) and synthesis of stable structurally characterized heterotetranuclear MoVI2CuI2 Complex. Molecules 2023, 28, 3644.
68. Blasczak, V.; Mckinnon, M.; Suntrup, L.; Aminudin, N. A.; Reed, B.; Groysman, S.; Ertem, M. Z.; Grills, D. C.; Rochford, J. Steric and lewis basicity influence of the second coordination sphere on electrocatalytic CO2 reduction by manganese bipyridyl complexes. Inorg. Chem. 2022, 61, 15784-15800.
​67. Kurup, S. S.; Woodland, N. M.; Lord, R. L.; Groysman, S. Aziridination reactivity of a manganese(II) complex with a bulky chelating bis(alkoxide) ligand. Molecules 2022, 27, 5751.
66. Kurup, S. S.; Groysman, S. Catalytic synthesis of azoarenes via metal-mediated nitrene coupling. Dalton Trans. 2022, 51, 4577-4589.
65. Dissanayake, A. I.; Hollingsworth, T. S.; Kurup, S. S.; Wannipurage, D.; Hamilton, P. N.; Lord, R. L.; Groysman, S. Synthesis, electronic structures, and reactivity of mononuclear and dinuclear low-valent molybdenum complexes in iminopyridine and bis(imino)pyridine ligand environments. J. Inorg. Biochem. 2022, 230, 111744.
64. Kurup, S. S.; Nasser, S.; Ward, C. L.; Groysman, S. Synthesis and structure of a new bulky bis(alkoxide) ligand on a terphenyl platform. Acta Crystallogr. E: Crystallogr. Commun. 2022, 78, 92-96.
63. Balch, A.; Everett, G.; Power, P. P.; Armstrong, W. H.; Kovacs, J.; Stack, T. D. P.; Donahue, J. P.; Gray, T. G.; Groysman, S.; Deng, L. Richard Hadley Holm: A remembrance and a tribute. Comments Inorg. Chem. 2021, 1-48.
62. Wannipurage, D.; Kurup, S. S.; Groysman, S. Heterocoupling of different aryl nitrenes to produce asymmetric azoarenes using iorn-alkoxide catalysis and investigation of the cis-trans isomerism of selected bulky asymmetric azoarenes. Organometallics 2021, 40, 3637-3644.
​​61. Kaluarachchige Don, U. I.; Kurup, S. S.; Hollingsworth, T. S.; Ward, C. L.; Lord, R. L.; Groysman, S. Synthesis and Cu(I)/Mo(VI) reactivity of a bifunctional heterodinucleating ligand on a xanthene platform. Inorg. Chem. 2021, 60, 14655-14666.
60. Groysman, S.; Grass, A. Alkoxide ligands, In Comprehensive Coordination Chemistry III, Constable, E. C.; Parkin, G.; Que, L., Jr, Eds, Elsevier 2021, 158-177.
59. Grass, A.; Kulathungage, L. W.; Wannipurage, D.; Yousif, M.; Ward, C. L.; Groysman, S. Synthesis, characterization, and alkoxide transfer reactivity of dimeric Tl2(OR)2 complexes. Dalton Trans. 2021, 50, 2501-2509.
58. Grass, A.; Bellow, J. A.; Morrison, G.; zur Loye, H.-C.; Lord, R. L.; Groysman, S. One electron reduction transforms high-valent low-spin cobalt alkylidene into high-spin cobalt(II) carbene radical. Chem. Commun. 2020, 56, 8416-8419.
57. Wannipurage, D.; Hollingsworth, T. S.; Santulli, F.; Cozzolino, M.; Lamberti, M.; Groysman, S.; Mazzeo, M. Synthesis of a mononuclear magnesium bis(alkoxide) complex and its reactivity in the ring-opening copolymerization of cyclic anhydrides with epoxides. Dalton Trans. 2020, 49, 2715-2723.
56. Kurup, S. S.; Staples, R. J.; Lord, R. L.; Groysman, S. Synthesis of chromium(II) complexes with chelating bis(alkoxide) ligand and their reactions with organoazides and diazoalkanes. Molecules 2020, 25, 373.
55. Grass, A.; Wannipurage, D.; Lord, R. L.; Groysman, S. Group-transfer chemistry at transition metal centers in bulky alkoxide ligand environments. Coord. Chem. Rev. 2019, 400, 1-16.
54. Kurup, S. S.; Wannipurage, D.; Lord, R. L.; Groysman, S. Tying the alkoxides together: an iron complex of a new chelating bulky bis(alkoxide) demonstrates selectivity for coupling of non-bulky aryl nitrenes. Chem. Commun. 2019, 55, 10780-10783.
53. Grass, A.; Stoian S. A.; Lord, R. L.; Groysman, S. Transition metal-mediated reductive coupling of diazoesters. Chem. Commun. 2019, 55, 8458-8461.
52. Grass, A.; Dewey. N. S.; Lord, R. L.; Groysman, S. Ketenimine Formation Catalyzed by a High Valent Cobalt Carbene in Bulky Alkoxide Ligand Environment. Organometallics 2019, 38, 962-972.
51. Hollingsworth, R. L.; Hollingsworth, T. S.; Groysman, S. Synthesis and Reactivity of Bimetallic Systems Tethered with a 4,5-Diaminoxanthene Linker. In Catalysis by Metal Complexes and Nanomaterials: Fundamentals and Applications; ACS Symposium Series 1317; American Chemical Society: Washington, DC, 2019; pp 1-18.
50. Hollingsworth, R. L.; Beattie, J. W.; Grass, A.; Martin, P. D.; Groysman, S.; Lord, R. L. Reactions of Dicobalt Octacarbonyl with Dinucleating and Mononucleating Bis(imino)pyridine Ligands. Dalton Trans. 2018, 47, 15353-15363.
49. Yousif, M.; Wannipurage, D.; Huizenga, C. D.; Washnock-Schmid, E.; Peraino, N. J.; Ozarowski, A.; Stoian, S. A.; Lord, R. L.; Groysman, S. Catalytic Nitrene Homocoupling by an Iron(II) Bis(alkoxide) Complex: Bulking Up the Alkoxide Enables a Wider Range of Substrates and Provides Insight into the Reaction Mechanism. Inorg. Chem. 2018, 57, 9425-9438.
48. Hollingsworth, T. S.; Hollingsworth, R. L.; Lord, R. L.; Groysman, S. Cooperative Bimetallic Reactivity of a Heterodinuclear Molybdenum-Copper model of Mo-Cu CoDH. Dalton Trans. 2018, 47, 10017-10024. ​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​
47. Hollingsworth, T. S.; Hollingsworth, R. L.; Rosen, T.; Groysman, S. Zinc Bimetallics Suppored by a Xanthene-Bridged Dinucleaing Ligand: Synthesis, Characterization, and Lactide Polymerization Studies. RSC Adv. 2017, 7, 41819-41829.
46. Reed, B. R.; Yousif, M.; Lord, R. L.; McKinnon, M.; Rochford, J.; Groysman, S. Coordination Chemistry and Reactivity of Bis(aldimino)pyridine Nickel Complexes in Four Different Oxidation States. Organometallics 2017, 36, 582-593.
45. Hollingsworth, R. L.; Bheemaraju, A.; Lenca, N.; Lord, R. L.; Groysman, S. Divergent Reactivity of a New Dinuclear Xanthene-Bridged Bis(iminopyridine) di-Nickel Complex with Alkynes. Dalton Trans. 2017, 46, 5605-5616.​
44. Narayanan, R.; McKinnon, M.; Reed, B. R.; Ngo, K. T.; Groysman, S.; Rochford, J. Ambiguous Electrocatalytic CO2 Reduction Behaviour of a Nickel Bis(aldimino)pyridine Pincer Complex. Dalton Trans. 2016, 45, 15285-15289.
43. Bellow, J. A.; Stoian, S. A.; Van Tol, J.; Ozarowski, A.; Lord, R. L.; Groysman, S. Synthesis and Characterization of a Stable High-Valent Cobalt Carbene Complex. J. Am. Chem. Soc. 2016, 138, 5531-5534
42. Yousif, M.; Cabelof, A. C.; Martin, P. D.; Lord, R. L.; Groysman S. Synthesis of a Mononuclear, Non-Square-Planar Chromium(II) Bis(alkoxide) Complex and its Reactivity Toward Organic Carbonyls and CO2. (Special Issue: New Talent: Americas), Dalton Trans. 2016, 45, 9794-9804. See Maryam's interview decribing this work here.
41. Beattie, J. W.; SantaLucia, D. J.; White, D. W.; Groysman. S. Oxalate- Templated Synthesis of Di-Zinc Macrocycles. Inorg. Chim. Acta. 2017, 460, 8-16. (Special Issue: New Generation)
40. Bellow, J. A.; Yousif, M.; Groysman, S. Discrete Complexes of 3d Metals with Monodentate Bulky Alkoxide Ligands and Their Reactivity in Bond Activation and Bond Formation Reactions. Comments Inorg. Chem. 2015, 36, 92-122.
39. Yousif, M.; Tjapkes, D.J.; Lord, R.L.; Groysman, S. Catalytic Formation of Asymmetric Carbodiimides at Mononuclear Chromium (II/IV) Bis(alkoxide) Complexes. Organometallics 2015, 34, 5119 - 5128.
38. Bellow, J. A.; Yousif, M.; Fang, D.; Kratz, E. G.; Cisneros, G. A.; Groysman, S. Synthesis and Reactivity of 3d Metal Complexes with the Bulky Alkoxide Ligand [OCtBu2Ph]. Inorg. Chem. 2015, 54, 5624- 5633.
37. Bellow, J. A.; Yousif, M.; Cabelof, A. C.; Lord, R.L.; Groysman, S. Reactivity Modes of an Iron Bis(alkoxide) Complex with Aryl Azides: Catalytic Nitrene Coupling vs Formation of Iron(III) Imido Dimers. Organometallics 2015, 34, 2917-2923.
36. Reed, B.R.; Stoian, S.A.; Lord, R.L.; Groysman S. The Aldimine Effect in Bis(imino)Pyridine Complexes: Non-Planar Nickel(I) Complexes of a Bis(aldimino)pyridine Ligand. Chem. Commun. 2015, 51, 6496-6499.
35. Bheemaraju, A.; Beattie, J.W.; Danylyuk, Y.; Rochford, J.; Groysman S. Synthesis, Structures, and Reactivity of Copper(I) Complexes Supported by a Rigid Dinucleating Ligand. Eur. J. Inorg. Chem. 2014, 34, 5865-5873.
34. Beattie, J. W.; White, D.S.; Bheemaraju, A.; Martin, P. D.; Groysman, S. Recyclable Chemosensor for Oxalate Based on Bimetallic Complexes of a Dinucleating Bis(iminopyridine) Ligand. Dalton Trans. 2014, 49, 7979-7986.
33. Bellow, J. A.; Martin, P. D.; Lord, R. L.; Groysman, S. Reductive Coupling of Azides Mediated by an Iron(II) Bis(alkoxide) Complex. Inorg. Chem. 2013, 52, 12335 -12337.
32. Bellow, J. A.; Fang, D.; Kovacevic, N.; Martin, P. D.; Shearer, J.; Cisneros, G. A.; Groysman, S. Novel Alkoxide Cluster Topologies Featuring Rare Seesaw Geometry at Transition Metal Centers. Chem. Eur. J. 2013, 19, 12225-12228.
31. Bheemaraju A.; Beattie, J. W.; Tabasan, E. G.; Martin, P. D.; Lord, R. L.; Groysman, S. Steric and Electronic Effects in the Formation of Carbon Disulfide Reactivity of Dinuclear Nickel Complexes Supported by Bis(iminopyridine) Ligands. Organometallics 2013, 32, 2952-2962.
30.Chambers, M. B.; Groysman, S.; Villigrán, D.; Nocera, D. G.; Iron in a Tris(alkoxide) Ligand Enviroment. Inorg. Chem. 2013, 52, 3159-3169.
29. Bheemaraju A.; Beattie, J. W.; Lord, R. L.; Martin, P. D.; Groysman, S. Carbon Disulfide Binding at Dinuclear and Mononuclear Nickel Complexes Ligated by a Redox-Active Ligand: Iminopyridine Serving as an Accumulator of Redox Equivalents for the Activation of Heteroallenes. Chem. Commun. 2012, 48, 9595-9597.
28. Bheemaraju A.; Lord, R. L.; Müller, P.; Groysman, S. Difference in the Reactivities of H- and Me-Substituted Dinucleating Bis(iminopyridine) Ligands with Nickel(0). Organometallics 2012, 31, 2120-2123.
27. Groysman, S.; Villagrán, D.; Freedman, D. E.; Nocera, D. G. Dinitrogen Binding at Vanadium in the Tris(alkoxide) Ligand Environment. Chem. Commun. 2011, 47, 10242-10244.
​26. Groysman, S.; Villagrán, D.; Nocera, D. G. Pseudo-tetrahedral d0, d1, and d2 Metal-Oxo Cores Within a Tris(alkoxide) Platform. Inorg. Chem. 2010, 49, 10759-10761.​
25. Groysman, S.; Majumdar, A.; Zheng, S.-L.; Holm, R. H. Reactions of Monodithiolene Tungsten(VI) Sulfido Complexes with Copper(I) in Relation to the Structure of the Active Site of Carbon Monoxide Dehydrogenase. Inorg. Chem. 2010, 49, 1082-1089.​
24. Groysman, S.; Holm, R. H. Biomimetic Chemistry of Iron, Nickel, Molybdenum, and Tungsten In Sulfur-Rich Protein Sites. Biochemistry 2009, 48, 2310-2320.
23. Groysman, S., Holm, R. H. A Series of Mononuclear Quasi-Two-Coordinate Copper(I) Complexes Employing a Sterically Demanding Thiolate Ligand. Inorg. Chem. 2009, 48, 621-627.
22. Groysman, S., Wang, J. - J., Tagore, R., Lee, S. C., Holm, R. H. A Biomimetic Approach to Oxidized Sites in the Xanthine Oxidoreductase Family: Synthesis and Stereochemistry of Tungsten(VI) Analogue Complexes. J. Am. Chem. Soc. 2008, 130, 12794-12807.
21. Wang, J. - J.; Groysman, S.; Lee, S. C.; Holm, R. H. Synthesis of Structural Analogues of the Oxidized Sites in the Xanthine Oxidoreductase Enzyme Family. J. Am. Chem. Soc. 2007, 129, 7512-7513.
​20. Groysman, S.; Holm, R. H. Synthesis and Structures of Bis(dithiolene) Tungsten (IV,VI) Thiolate and Selenolate Complexes: Approaches to the Active Sites of Molybdenum and Tungsten Formate Dehydrogenases. Inorg. Chem. 2007, 46, 4090-4102.​
19. Groysman, S.; Sergeeva, E.; Goldberg, I.; Kol, M. Zinc Complexes of the Amine Mono(phenolate) [NOO2] Ligands: Controlling Coordination Modes by Bulk of Phenolate Substituents. Eur. J. Inorg. Chem. 2006, 14, 2739-2745.
​18. Kol, M., Segal, S., Groysman, S. 2008. Stereocontrol in the Polymerization of C4+ α-olefin Monomers. In Stereoselective Polymerization with Single-Site Catalysts L. S. Baugh, J. A. M. Canich Boca Raton, FL.​
17. Gendler, S.; Groysman, S.; Goldschmidt, Z.; Shuster, M.; Kol, M.. Polymerization of 4-methylpentene and Vinylcyclohexane by the Amine Bis(phenolate) Group IV catalysts. J. Polym. Sci., Part A: Polym. Chem. 2006, 44, 1136-1146.
​16. Groysman, S.; Sergeeva, E.; Goldberg, I.; Kol, M. Group IV Complexes of a Tetradentate Amine Mono(phenolate) Ligand: a Second Sidearm Donor Stabilizes Cationic Species. Inorg. Chem. 2005, 44, 8188-8190.​
15. Yeori, A.; Groysman, S.; Goldberg, I.; Kol, M. Diastereoisomerically-Selective Enantiomerically-Pure Titanium Complexes of Chiral Salan Ligands. Inorg. Chem. 2005, 44, 4466-4467.​
14. Groysman, S.; Goldberg, I.; Kol, M.; Goldschmidt, Z. Vanadium(III) and Vanadium(V) Amine Tris(phenolate) Complexes. Inorg. Chem. 2005, 44, 5073-5080.​
13. Groysman, S.; Sergeeva, E.; Goldberg, I.; Kol. M. Salophan complexes with Group IV Metals. Eur. J. Inorg. Chem. 2005, 12, 2480-2485.​
12. Groysman, S.; Goldberg, I., Kol, M., Genizi, E., Goldshmidt, Z. Exploring Routes to Tantalum (V) Alkyl and Alkylidene Complexes Supported by the Amine Tris(Phenolate) ligands. Adv. Syn. Cat. 2005, 347, 409-415.
11. Groysman, S.; Tshuva, E.; Goldberg, I.; Kol, M.; Goldschmidt, Z.; Shuster, M. Diverse Structure-Activity Trends in the Amine Bis(phenolate) Titanium Polymerization Catalysts. Organometallics 2004, 23, 5291-5299.​
10. Groysman, S.; Segal, S.; Goldberg, I.; Kol, M.; Goldschmidt, Z. Ta(V) Complexes of a Bulky Amine Tris(phenolate) Ligand: Steric Inhibition vs. Chelate Effect. Inorg. Chem. Commun. 2004, 7, 938-941.
​9. Groysman, S.; Goldberg, I.; Kol, M.; Genizi, E.; Goldschmidt, Z. Tribenzyl Ta(V) Complexes of Amine Bis(phenolate) Ligands: Investigation of α-Abstraction vs. Ligand Backbone β-Abstraction Paths. Organometallics 2004, 23, 1880-1890.​
8. Yeori, A.; Gendler, S.; Groysman, S.; Goldberg, I.; Kol. M. Salalen: a Hybrid Salan/Salen Tetradentate [ONNO]-Type Ligand and Its Coordination Behavior with Group IV Metals. Inorg. Chem. Commun. 2004, 7, 280-282.​
7. Groysman, S.; Goldberg, I.; Kol, M.; Goldschmidt Z. Pentabenzyltantalum: Straightforward Synthesis, X-ray Structure and Application in the Synthesis of [O2N]TaBn3-Type and [O3N]TaBn2-Type complexes. Organometallics 2003, 22, 3793-3795.​
6. Groysman, S.; Goldberg, I.; Kol, M.; Genizi, E.; Goldschmidt, Z. From THF to Furan: Activity Tuning and Mechanistic Insight via Sidearm Donor Replacement in Group IV Amine Bis(phenolate) Polymerization Catalysts. Organometallics 2003, 22, 3013-3015.
​5. Groysman, S.; Tshuva, E. Y.; Reshef, D.; Gendler, S.; Goldberg, I.; Kol, M.; Goldschmidt, Z.; Shuster, M.; Lidor, G. High-Molecular Weight Atactic Polypropylene prepared by Zirconium Complexes of an Amine Bis(phenolate) Ligand. Isr. J. Chem. 2003, 42, 373-381.
4. Groysman, S.; Goldberg, I.; Kol, M.; Genizi, E.; Goldschmidt, Z. Group IV complexes of an Amine Bis(phenolate) Ligand Featuring a THF Sidearm Donor: From Highly Active to Living Polymerization Catalysts of 1-Hexene. Inorg. Chim. Acta 2003, 345, 137-144. (Protagonists in Chemistry: R. R. Schrock Issue)​
3. Bergman, S.; Reshef, D.; Groysman, S.; Goldberg, I.; Kol, M., Dibenzoeilatin: A Novel Ligand Exhibiting Remarkable Complementary π-π Stacking Interactions. Chem. Commun. 2002, 2374-2375.​
2. Groysman, S.; Segal, S.; Shamis, M.; Goldberg, I.; Kol, M.; Goldschmidt, Z.; Hayut-Salant, E. Tantalum(V) Complexes of an Amine Triphenolate Ligand: a Dramatic Difference in Reactivity Between Two Labile Positions. J. Chem. Soc., Dalton Trans. 2002, 3425-3426.
​​​1. Tshuva, E. Y.; Groysman, S.; Goldberg, I.; Kol, M.; Goldschmidt, Z. [ONXO]-Type Amine Bis(phenolate) Zirconium and Hafnium Complexes as Extremely Active 1-hexene Polymerization Catalysts. Organometallics 2002, 21, 662-670.